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Synthesis of Pyrite FeS2 Nanospheres and Study on the Supercapacitor Performance
LI Jianzhuo, CHUAN Xiuyun
Acta Scientiarum Naturalium Universitatis Pekinensis    2021, 57 (4): 623-631.   DOI: 10.13209/j.0479-8023.2021.058
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Pyrite FeS2 nanospheres was synthesized through a simple solvothermal method in one step, and the electrochemical performance as the electrode material of supercapacitor was studied. The structure, morphology, specific surface area and pore volume of the material were characterized and measured experimentally, and its supercapacitor performances in three common electrolytes (6 M KOH, 6 M NaOH and 1 M Na2SO4) were tested by cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) and electrochemical impedance spectroscopy (EIS). The results show that the product is homogeneous pyrite FeS2 nanospheres with a diameter of about 300?600 nm, showing obvious pseudocapacitance characteristics in all three electrolytes. When the electrolyte is KOH, it shows the highest specific capacitance, reaching 732.9 F/g at the current density of 2 A/g and 307.1 F/g at the current density of 20 A/g with the capacity retention rate of 41.9%. It is demonstrated that the synthesized FeS2 nanospheres is an excellent electrode material for supercapacitors. 
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Mineralogical Characteristics of Aphanitic Cryptocrystalline in Yantongshan and Its Significance for Origin
CHENG Siyu, CHUAN Xiuyun, YANG Yang, LIN Chao, CHEN Siyu
Acta Scientiarum Naturalium Universitatis Pekinensis    2020, 56 (2): 242-252.   DOI: 10.13209/j.0479-8023.2019.126
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By means of optical microscope, field emission scanning electron microscope, X-ray diffraction and laser Raman spectroscopy, the mineralogical characteristics of cryptocrystalline graphite in Yantongshan, Jilin Province and its indication significance for the genesis of the deposit are studied. The diameter of graphite microcrystals is La=59?175 nm, and the stacking height is Lc=32?93 nm. The graphitization degree value ranges from 0.573 to 1.000, and the interval (002) layers vary from 0.3352 to 0.3370 nm. The intensity ratio of D1 peak and G peak arranges between 0.07 to 0.28. On the base above, the metamorphic temperature range was calculated as 526℃ to 622℃, with the average is 561℃, indicating that the metamorphic degree could reach the amphibolite facies in its formation. The graphitization degree varied greatly, and much higher near Fe bearing minerals, indicating that the crystallization process of graphite could be catalyzed with the different spots of one graphite ore slice by Fe containing compounds.
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Oxidation Modification of Natural Molybdenite Using Concentrated Sulfuric Acid and Its Electrocatalytic Properties
QIANG Jingya, CHUAN Xiuyun
Acta Scientiarum Naturalium Universitatis Pekinensis    2018, 54 (3): 579-584.   DOI: 10.13209/j.0479-8023.2017.083
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The purified molybdenite were obtained using concentrated sulfuric acid and heating oxidation method, and the samples before and after oxidation were characterized systematically based on X-ray fluorescence spectrum (XRF), powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and Raman spectroscopy. Moreover, its electrocatalytic properties were tested and analyzed. The results show that the average grain size of MoS2 (002) crystal plane direction decreases by 14% and interlayer spacing increases 0.04Å after concentrated sulfuric acid oxidation, and S2− is oxidized into S6+, indicating that layers of Molybdenite can be stripped through oxidation. The reductive peak of potential move forward after oxidation, implying reduction enhancement on p-nitrophenol.

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